Optimized monotonic convex pair potentials stabilize low-coordinated crystals
نویسندگان
چکیده
We have previously used inverse statistical-mechanical methods to optimize isotropic pair interactions with multiple extrema to yield low-coordinated crystal classical ground states (e.g., honeycomb and diamond structures) in d-dimensional Euclidean space R. Here we demonstrate the counterintuitive result that no extrema are required to produce such low-coordinated classical ground states. Specifically, we show that monotonic convex pair potentials can be optimized to yield classical ground states that are the square and honeycomb crystals in R over a non-zero number density range. Such interactions may be feasible to achieve experimentally using colloids and polymers.
منابع مشابه
Unusual ground states via monotonic convex pair potentials.
We have previously shown that inverse statistical-mechanical techniques allow the determination of optimized isotropic pair interactions that self-assemble into low-coordinated crystal configurations in the d-dimensional Euclidean space R(d). In some of these studies, pair interactions with multiple extrema were optimized. In the present work, we attempt to find pair potentials that might be ea...
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